Related Experiment Videos
[IR spectra and structures of two trinuclear molybdenum cluster compounds coordinated by binary carboxylates]
1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, 350002 Fuzhou.
Guang Pu Xue Yu Guang Pu Fen Xi = Guang Pu
|August 30, 2003
Abstract:
Two trinuclear molybdenum cluster compounds coordinated by binary carboxylates compounds Mo3S4 (DTP)3(phthalate) (Py)(A) and Mo3S4 (DTP)3(malonate)(Py)(B) have been synthesized. IR absorption peaks of Mo3S4 core and the ligands are assigned with reference to those of Mo3S4(DTP)4(Py)(C). The assignment of stretching vibrations of carboxylate (COO-) for both (A) and (B) reveals much information corresponding to their molecular structures.