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Generation of an equilibrating collection of crystalline solids from a dynamic combinational library
Ke-liang Pang1, Dong Guo, Chun-ying Duan
1Coordination Chemistry Institute, the State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, PR China.
Inorganic Chemistry
|September 3, 2003
Abstract:
Thermodynamically controlled crystallization of a copper-containing building block [CuL] (H(2)L = 2-(2'-hydroxyphenyl)-Delta(2)-thiazoline-4-carboxylic acid) from a methanol-ethanol mixture solvent leads to a combinatorial mixture of four crystalline solids, from which each of them is isolated and structurally characterized.