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Diastereoselective intramolecular SmI2-H2O-amine mediated couplings
Anders Dahlén1, Annika Petersson, Göran Hilmersson
1Department of Chemistry, Göteborg University, SE-41296 Göteborg, Sweden.
Organic & Biomolecular Chemistry
|September 6, 2003
Abstract:
The SmI2-H2O-amine mixture has been shown to be effective for intramolecular couplings providing diastereoselectivities of up to 100% de in the coupling of O-cyclohexenyliodophenol derivatives into heterocycles.