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Updated: Aug 9, 2026

Synthesis of Nine-atom Deltahedral Zintl Ions of Germanium and their Functionalization with Organic Groups
Published on: February 11, 2012
[Ge9=Ge9=Ge9=Ge9]8-: a linear tetramer of nine-atom germanium clusters, a nanorod
1Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556, USA.
Abstract:
A tetramer of nine-atom deltahedral germanium clusters and charge 8-, [Ge9=Ge9=Ge9=Ge9]8- , has been characterized as a (Rb-18C6)(+) salt (18C6 = 18-crown-6 polyether). The clusters are connected by pairs of parallel bonds, and the electrons are delocalized over the whole anion. The size of the tetramer is of nanorod dimensions, ca. 2 nm.
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