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Total asymmetric synthesis of sperabillins B and D
Stephen G Davies1, Richard J Kelly, Anne J Price Mortimer
1Dyson Perrins Laboratory, University of Oxford, South Parks Road, Oxford, UK OX1 3QY. steve.davies@chemistry.ox.ac.uk
Chemical Communications (Cambridge, England)
|September 19, 2003
Abstract:
A concise route to the core fragment of sperabillins B and D, methyl (3R,5R,6R)-3,6-diamino-5-hydroxyheptanoate, has been developed with a subsequent novel protection strategy allowing the total asymmetric synthesis of sperabillins B and D.