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Updated: Sep 13, 2026

A Novel Technique for Generating and Observing Chemiluminescence in a Biological Setting
Published on: March 9, 2017
Luminescent heterohexanuclear complexes with platinum alkynyl and silver diphosphine as components
Qiao-Hua Wei1, Gang-Qiang Yin, Zhen Ma
1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.
Abstract:
Reactions between the building blocks [Ag2(mu-Ph2PXPPh2)2(MeCN)2]2+ and [Pt(C[triple bond]CC6H4R-p)4]2- (R = H, CH3) afforded strongly luminescent acetylide-linked neutral heterohexanuclear complexes Pt2Ag4(mu-Ph2PNPPh2)4 (C[triple bond]CC6H4R-p)4 (R = H, 1; CH3, 2) for X = NH, but a heterotrinuclear complex cation [PtAg2(mu-PPh2CH2PPh2)2 (C[triple bond]CC6H5)2(CH3CN)2]2+ (3(2+)) for X = CH2.
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