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Preparation of potential anti-inflammatory agents from dehydroabietic acid

W S Li1, J D McChesney

  • 1Department of Agricultural Chemistry, National Pingtung Institute of Agriculture, Taiwan, Republic of China.

Journal of Pharmaceutical Sciences
|July 1, 1992
PubMed

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Preparation of Acid Anhydrides01:07

Preparation of Acid Anhydrides

One of the methods for preparing symmetrical or unsymmetrical acid anhydrides involves the treatment of acid chlorides with the sodium salt of carboxylic acids. The reaction proceeds via a nucleophilic acyl substitution.
The carboxylate ion acts as a nucleophile that attacks the carbonyl carbon of the acid chloride to form a tetrahedral intermediate. Subsequently, the re-formation of the carbonyl group with the loss of the chloride ion as a leaving group leads to the formation of an acid...