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New routes to high nuclearity cages: dimerisation of a manganese triangle via solvothermal synthesis
David M Low1, Euan K Brechin, Madeleine Helliwell
1Department of Chemistry, The University of Manchester, Oxford Road, Manchester, UK M13 9PL.
Abstract:
Heating [Mn3O(O2CPh)6(py)2(H2O)] in MeCN at 100 degrees C for 12 hours in a sealed Teflon container produces the hexanuclear species [Mn6O2(O2CPh)12(py)2]: dimerisation of the triangle occurs via solvent loss and ligand rearrangement.
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