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Probing electronic states of Ne2+ and Ar2+ by measuring kinetic-energy-release distributions
J Fedor1, R Parajuli, S Matt-Leubner
1Institut für Ionenphysik, Leopold Franzens Universität, Technikerstrasse 25, A-6020 Innsbruck, Austria.
Abstract:
Dissociative decay of metastable, electronically excited neon and argon dimer ions produces fragment ions with strikingly dissimilar kinetic-energy-release distributions. The distributions have been modeled based on ab initio calculations of potential energy curves. The unusual bimodal distribution observed for dissociation of Ne2+ arises from competition between radiative and nonradiative decay of the long-lived II(1/2)(u) state. For Ar2+, however, electronic predissociation is insignificant.
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