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Updated: Jul 13, 2026

Fabricating Reactive Surfaces with Brush-like and Crosslinked Films of Azlactone-Functionalized Block Co-Polymers
Published on: June 30, 2018
Shell cross-linked cylinders of polyisoprene-b-ferrocenyldimethylsilane: formation of magnetic ceramic replicas and
Xiao-Song Wang1, André Arsenault, Geoffrey A Ozin
1Center for Nanostructured Inorganic and Polymeric Materials, Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada M5S 3H6.
Abstract:
Stable organometallic cylindrical nanostructures have been prepared by shell cross-linking of PI320-b-PFS53 wormlike micelles in hexane through metal-catalyzed hydrosilylation at 23 degrees C. The cross-linked structures permit the formation of cylindrical ceramic replicas containing size- and separation-tunable arrays of Fe nanoclusters. In addition, microfluidic alignment of the cross-linked cylinders was possible.
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