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Determination of the absolute P-configuration of a phthalidyl-phosphonate thymidine-thymidine dimer

W Fendrich1, C Meier

  • 1Institute of Organic Chemistry, University of Hamburg, Hamburg, Germany.

Nucleosides, Nucleotides & Nucleic Acids
|October 21, 2003
PubMed

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Chirality at Nitrogen, Phosphorus, and Sulfur02:30

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Chirality is most prevalent in carbon-based tetrahedral compounds, but this important facet of molecular symmetry extends to sp3-hybridized nitrogen, phosphorus and sulfur centers, including trivalent molecules with lone pairs. Here, the lone pair behaves as a functional group in addition to the other three substituents to form an analogous tetrahedral center that can be chiral.
A consequence of chirality is the need for enantiomeric resolution. While this is theoretically possible for all...