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A new hydrated ammonium hydroxyborate, (NH(4))(2)[B(10)O(14)(OH)(4)].H(2)O
Lin-Yan Li1, Guo-Bao Li, Ming Xiong
1State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, People's Republic of China.
Abstract:
The structure of a new synthetic compound, diammonium tetrahydroxydecaborate monohydrate, has been determined by single-crystal X-ray diffraction. It crystallizes in triclinic space group P-1 and all atoms occupy general sites. The title compound is composed of [B(10)O(15)(OH)(4)](4-) ions as the fundamental building blocks, and these are linked end-to-end by sharing two common O atoms, thus producing infinite chains of composition [B(10)O(14)(OH)(4)](n)(2n-). These chains are linked by hydrogen bonds, thus forming borate sheets. Water molecules and ammonium ions between these sheets connect adjacent sheets via hydrogen bonds.