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Updated: Jul 7, 2026

Fabrication, Densification, and Replica Molding of 3D Carbon Nanotube Microstructures
Published on: July 2, 2012
Synergy between spin crossover and metallophilicity in triple interpenetrated 3D nets with the NbO structure type
Ana Galet1, Virginie Niel, M Carmen Muñoz
1Departament de Física Aplicada, Universitat Politècnica de València, Camino de Vera s/n, 46022 València, Spain.
Abstract:
Self-assembly of [Ag(CN)2]-, 3-cyanopyridine, and iron(II) gives triple interpenetration of three-dimensional spin crossover (SCO) networks with the NbO topology, which interact each other via argentophilic interactions. Superposition of the networks along the c-axis defines an infinite mosaic of trigonal and hexagonal cross-sectional tubes where water molecules are installed. The structural changes associated with the SCO tune the homoatomic interactions and induce an uncommon change of the lattice volume.
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