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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
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Polarizing the Nazarov cyclization: efficient catalysis under mild conditions.

Wei He1, Xiufeng Sun, Alison J Frontier

  • 1Department of Chemistry, University of Rochester, Rochester, NY 14627, USA.

Journal of the American Chemical Society
|November 20, 2003
PubMed
Summary

Substituted divinyl ketones efficiently undergo Nazarov cyclization using copper triflate catalysis. This reaction yields a single cyclopentenone isomer, with efficiency depending on substituent electronic effects.

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