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Updated: Aug 30, 2026

Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of Chalcogenidoplumbates(II or IV)
Published on: December 29, 2016
Structure and physical properties of 1D magnetic chalcogenide, jamesonite (FePb4Sb6S14)
Yoshitaka Matsushita1, Yutaka Ueda
1Materials Design and Characterization Laboratory, Institute for Solid State Physics (ISSP), The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8581 Japan. chaos@issp.u-tokyo.ac.jp
Abstract:
Monoclinic FePb(4)Sb(6)S(14) phase, jamesonite, which is a candidate material as a S = 2 Haldane compound, has been synthesized by the direct reaction of elements under dry conditions with sealed evacuated quartz tubes. The congruent melting point was determined at 592 degrees C by DTA measurements. Shiny metallic gray needle crystals grow on the surface of bulk heated at 550 degrees C. The elongated direction of each needle crystal is parallel to the c-axis. The crystal structure refinement (P2(1)/a, a = 15.750(6) A, b = 19.125(3) A, c = 4.030(4) A, beta = 91.68(8) degrees, V = 1213(1) A(3), Z = 2, D(c) = 5.651 g/cm(3), R(1) = 3.16%) reveals the presence of two rod substructures elongated parallel to the c-axis. One is the lozenge-shaped Bi(2)Te(3)-type (or called SnS archetype), [Pb(4)Sb(6)S(13)]. The other is the novel single magnetic one-dimensional (1D) straight chain, [FeS(6)]. This compound shows intrinsic semiconductor behavior in the electric conductivity measurements. The optical band gap, 0.48 eV, is estimated by near-IR diffuse reflectance measurements. In the magnetic susceptibility measurements, this compound shows 1D-Heisenberg antiferromagnetic behavior with a broad peak at approximately 33.5 K, where Fe(2+) takes the high-spin state, t(2g)(4)e(g)(2). A possibility for the S = 2 Haldane system is discussed.
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