The potential use of continuous-flow isotope-ratio mass spectrometry as a tool in forensic soil analysis: a...

The use of continuous-flow isotope-ratio mass spectrometry (CF-IRMS) as a tool in soil analysis has been assessed as part of a larger study using a number of geological techniques applied in a forensic context. Carbon and nitrogen isotopic ratios, delta13C and delta15N, have been analysed to investigate situations which have arisen from crime casework. Three questions have been addressed: the role of spatial variation found over the short-scale (less than 20 m), temporal variation over a period of almost 2 years, and the variation found between source soils and soil transferred to footwear soles during a simple one-stage transfer process. Results are presented for the three experiments. The use of carbon and nitrogen isotopes has been shown to be useful in discriminating between soil types and sample locations, even when sampling occurs at a different time (as might be the case with a crime scene). In cases of primary transfer (from a source soil by a one-stage transfer to another surface, in this case, shoes and boots), the combination of carbon and nitrogen isotope ratios is a valuable tool in discriminating between sites and in showing the relationship of the transferred samples to the relevant source soils. Used in combination with other analytical techniques, isotopic analysis may prove to be a useful tool in a forensic context.