Behavior of gasoline pools following a denatured ethanol spill

In 1999, approximately 72 m3 of denatured fuel-grade ethanol spilled at a bulk fuel terminal that had existing contamination within the subsurface. An unanticipated increase in the measured depth of the light nonaqueous phase liquid (LNAPL) was observed in nearby monitoring wells following the spill. This paper presents results of a laboratory analysis designed to understand the apparent increase in LNAPL mobility at this site. The two-dimensional stainless steel and glass tank allowed visual assessment of the potential effects that the addition of denatured ethanol may have on a site with pre-existing gasoline contamination. Digital images of gasoline and ethanol spill experiments were analyzed for changes in the characteristics of the existing gasoline pool and residual gasoline saturation in the unsaturated zone. Reductions in the surface and interfacial tensions resulted in significant changes in the size, shape, and saturation of the gasoline pool after the addition of ethanol to the system. The final gasoline pool occupied a smaller area and had a higher saturation. In addition, some smearing of the gasoline into the saturated zone occurred as the capillary fringe was depressed.