Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

Improved transparency--nonlinearity trade-off with boroxine-based octupolar molecules.

Gilles Alcaraz1, Lisenn Euzenat, Olivier Mongin

  • 1Synthèse et ElectroSynthèse Organiques (CNRS, UMR 6510), Université de Rennes 1, Institut de Chimie, Campus Scientifique de Beaulieu, Bât 10A, F-35042 Rennes Cedex, France.

Chemical Communications (Cambridge, England)
|December 4, 2003
PubMed
Summary

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Constructing density functional tight-binding parameters for electronic structure modeling of lead-bromide perovskites, perovskitoids, and related structures.

The Journal of chemical physics·2026
Same author

Safety, feasibility and preliminary effects of Atalante exoskeleton-assisted gait training in amyotrophic lateral sclerosis: a prospective ABA pilot study.

Journal of neuroengineering and rehabilitation·2026
Same author

Molecular engineering of individual dye-based nanoparticle photostability for ultrabright two-photon fluorescence.

Beilstein journal of nanotechnology·2026
Same author

Expanding educational access for rural healthcare professionals through mobile simulation: A scoping review.

Nurse education in practice·2026
Same author

Prospective gait analysis in patients from the French registry of glycogen storage disease type III: implications for clinical trials.

Journal of neurology·2026
Same author

Bypassing the yellow phase for extremely stable formamidinium lead iodide perovskite solar cells.

Science (New York, N.Y.)·2026

New octupolar molecules based on the boroxine framework exhibit high optical nonlinearities and transparency. These materials are promising for applications requiring efficient light manipulation in the UV-visible spectrum.

Area of Science:

  • Materials Science
  • Optics
  • Chemistry

Background:

  • Octupolar molecules are of interest for nonlinear optics.
  • Boroxine frameworks offer a versatile platform for molecular design.

Purpose of the Study:

  • To design and synthesize novel octupolar molecules utilizing a boroxine framework.
  • To investigate the optical nonlinearities and transparency of these new molecules.

Main Methods:

  • Synthesis of boroxine-derived octupolar molecules.
  • Harmonic light scattering experiments in solution to measure optical nonlinearities.
  • UV-visible spectroscopy to assess transparency.

Main Results:

  • The designed molecules exhibit excellent transparency in the near UV-visible region (lambda_max <= 280 nm).

Related Experiment Videos

  • Significant first-order hyperpolarizabilities (beta(0)) were measured, reaching up to 56 x 10(-30) esu.
  • The boroxine framework effectively supports the development of molecules with desirable nonlinear optical properties.

    • Conclusions:

    • Boroxine-based octupolar molecules represent a promising class of materials for nonlinear optical applications.
    • These molecules offer a combination of high optical nonlinearity and good transparency.
    • Further research can explore structural modifications for enhanced performance.