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Updated: Jun 26, 2026

Spatial Separation of Molecular Conformers and Clusters
Published on: January 9, 2014
Subkelvin cooling NO molecules via "billiard-like" collisions with argon
Michael S Elioff1, James J Valentini, David W Chandler
1Combustion Research Facility, Sandia National Laboratories, Livermore, CA 94550, USA.
Abstract:
We report the cooling of nitric oxide using a single collision between an argon atom and a molecule of NO. We have produced significant numbers (108 to 109 molecules per cubic centimeter per quantum state) of translationally cold NO molecules in a specific quantum state with an upper-limit root mean square laboratory velocity of 15 plus or minus 1 meters per second, corresponding to a 406 plus or minus 23 millikelvin upper limit of temperature, in a crossed molecular beam apparatus. The technique, which relies on a kinematic collapse of the velocity distributions of the molecular beams for the scattering events that produce cold molecules, is general and independent of the energy of the colliding partner.
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