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Twinned alpha-LiRb2(CF3SO3)3.

M Pompetzki¹, K Friese, M Jansen

¹Max-Planck Institut für Festkörperforschung, Heisenbergstrasse 1, D-70569 Stuttgart, Germany.

Acta Crystallographica. Section C, Crystal Structure Communications

|December 13, 2003

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This study details the crystal structure of alpha-lithium dirubidium tris(trifluoromethanesulfonate). The structure features unique channel-like patterns formed by trifluoromethanesulfonate groups and distinct cation coordination environments.

Area of Science:

Solid-state chemistry
Crystallography
Materials science

Background:

Understanding the structural properties of ionic compounds is crucial for developing new materials.
Lithium and rubidium salts of trifluoromethanesulfonate are of interest for their potential applications.

Purpose of the Study:

To elucidate the detailed crystal structure of alpha-lithium dirubidium tris(trifluoromethanesulfonate).
To characterize the coordination environments of lithium and rubidium cations within the crystal lattice.

Main Methods:

Single-crystal X-ray diffraction was employed to determine the crystal structure.
Analysis of atomic coordinates and bond lengths/angles to describe coordination polyhedra.

Main Results:

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The crystal was identified as a twin with a specific twin matrix.
A unique structure featuring channel-like arrangements of trifluoromethanesulfonate groups was observed.
Distinct coordination geometries were found for the rubidium cations (distorted square antiprism and distorted pentagonal plane) and the lithium cation (distorted tetrahedron).

Conclusions:

The crystal structure of alpha-LiRb(2)(CF(3)SO(3))(3) exhibits a complex arrangement of ions and functional groups.
The diverse coordination environments suggest potential for varied interactions and properties within the material.