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Lead bismuth calcium sodium phosphate: Pb4.6Bi0.4Ca2.6Na2.4(PO4)6
Besma Hamdi1, Jean-Michel Savariault, Hafed El-Feki
1Laboratoire de Sciences de Matériaux et d'Environnement, Faculté des Sciences de SFAX, BP 802, 3018 SFAX, Tunisia.
Abstract:
The title compound, lead bismuth calcium sodium phosphate, Pb(4.6)Bi(0.4)Ca(2.6)Na(2.4)(PO(4))(6) crystallizes in the apatite structure type, with vacancies in sites 2a or 2b that are normally occupied by anions. The fact that the Bi and Pb ions are mainly localized in the 6h sites confirms the electron lone-pair influence on the apatite structure.
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