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High-resolution NMR spectra in inhomogeneous fields via IDEAL (intermolecular dipolar-interaction enhanced all lines)
Zhong Chen1, Zhiwei Chen, Jianhui Zhong
1Department of Radiology, University of Rochester, Rochester, New York 14642, USA. chenz@jingxian.xmu.edu.cn
Abstract:
Intermolecular double-quantum technique is used to yield high-resolution NMR spectra in inhomogeneous magnetic fields. The method exploits the distant dipolar interactions between the solvent and solute nuclear spins. Chemical shifts, J couplings, multiplicity patterns, and relative areas are retained with the method. Except for a 1.5-fold change in the scale factor of J couplings, other parameters are consistent with those extracted from one-dimensional spectra obtained in a homogeneous field.
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