Related Experiment Video
Updated: Aug 29, 2026

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
Published on: December 4, 2017
Simple analytic equations of state for hard-core single and double Yukawa fluids and mixtures based on second-order
1Department of Applied Physics, University of Electronic Science and Technology, Chengdu 610054, People's Republic of China.
Abstract:
A simple analytic expression with high precision for the radial distribution function of hard spheres is proposed. The form of the expression has been carefully selected to combine the well-known Camahan-Starling equation of state in it and satisfy the limit condition at low density, its simplicity and precision is superior to the well-known Percus-Yevick expression. The coefficients contained in the expression have been determined by fitting the Monte Carlo data for the first coordination shell, and by fitting both the Monte Carlo data and the numerical results of the Percus-Yevick expression for the second coordination shell. The expression has been applied to develop simple analytic equations of state for the hard-core single, double Yukawa fluids, and the hard-core Yukawa mixtures. The comparisons show that the agreement of our model with the computer simulation data is slightly better than the mean spherical approximation and other analytic models.
Related Concept Videos
Equation of State
Euler's Equations of Motion
Linear Approximation in Time Domain
For a simple pendulum with a mass evenly distributed along its length and the center of mass located at half the pendulum's length, the...
Van der Waals Equation
First, the attractive forces between molecules, which are stronger at higher densities and reduce the pressure, are considered by adding to the pressure a term equal to the square of the molar density multiplied by a positive coefficient a. Second, the volume...
Variables and Equations of State
Partial Derivatives and Gas Laws