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Preparation of acentric porous coordination frameworks from an interpenetrated diamondoid array through

Miao Du1, Ya-Mei Guo, Shen-Tan Chen

  • 1Department of Chemistry, Nankai University, Tianjin 300071, PR China.

Inorganic Chemistry
|February 18, 2004
PubMed

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Crystal Field Theory
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Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
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Stereoisomerism

Isomerism in Complexes
Isomers are different chemical species that have the same chemical formula.
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