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Cumene oxidation by cis-[RuIV(bpy)2(py)(O)]2+, revisited

Jasmine R Bryant1, Takashi Matsuo, James M Mayer

  • 1Department of Chemistry, University of Washington, Box 351700, Seattle, Washington 98195-1700, USA.

Inorganic Chemistry
|February 18, 2004
PubMed
Summary

Ruthenium oxo complexes oxidize cumene via hydrogen atom transfer, not hydride transfer. This study clarifies the oxidation mechanism and products, challenging previous findings.

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