Quantification of oxygen fluxes in a long gravity sewer

Quantification of the oxygen fluxes in the sewer system is at present the optimal methodology to obtain information about the influence of sewers on transformations and mass balances in the urban drainage system. However, the relative and absolute values of these fluxes are practically unknown. In this work, the oxygen fluxes were quantified experimentally in a full-scale aerobic main sewer. The sewer biofilm respiration was determined with an in situ flow cell, a method that has not been used before in the sewer. The surface reaeration was determined with a gas tracer method based on the inert, non-radio-active and non-toxic gas tracer sulphur hexafluoride. In addition, the wastewater biomass respiration rate was measured. The validity of the applied methods was verified with redundant oxygen balances over a 2-km-long section. Measurement campaigns under different hydrodynamic conditions showed that the relative contribution of the biofilm, the wastewater, the reaeration and the in- and outflow with the water, all contributed significantly. However, the absolute contributions varied extensively and depended especially on the discharge. The COD conversion in the sewer could be estimated from the aerobic activity. The aerobic total degradation in the study reach was 3%. However, when extrapolated to the entire sewer net of the catchment area with 5000 PE, the COD conversion was estimated as high as 30% of the dissolved COD during the night. This indicates that the wastewater composition at the treatment plant will be strongly affected by the sewer system.