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Heterogeneous Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst from Aqueous Media Via Host-Guest Interaction
Published on: August 23, 2018
Ambient temperature, tandem catalytic dehydrocoupling-hydrogenation reactions using Rh colloids and Me2NH.BH3 as a
1Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada M5S 3H6.
Journal of the American Chemical Society
|March 5, 2004
Abstract:
Highly active Rh colloids, generated in situ during the catalytic dehydrocoupling of Me2NH.BH3 using [{Rh(cod)(mu-Cl)}2] as a precatalyst, are capable of efficiently hydrogenating alkenes at 25 degrees C in a one-pot procedure using only the evolved H2 from the initial dehydrocoupling reaction.
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