Related Experiment Video
Updated: Aug 26, 2026

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
Published on: December 4, 2017
Nature of slow dynamics in a minimal model of frustration-limited domains
Phillip L Geissler1, David R Reichman
1Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.
Abstract:
We present simulation results for the dynamics of a schematic model based on the frustration-limited domain picture of glass-forming liquids. These results are compared with approximate theoretical predictions analogous to those commonly used for supercooled liquid dynamics. Although model relaxation times increase by several orders of magnitude in a non-Arrhenius manner as a microphase separation transition is approached, the slow relaxation is in many ways dissimilar to that of a liquid. In particular, structural relaxation is nearly exponential in time at each wave vector, indicating that the mode-coupling effects dominating liquid relaxation are comparatively weak within this model. Relaxation properties of the model are instead well reproduced by the simplest dynamical extension of a static Hartree approximation. This approach is qualitatively accurate even for temperatures at which the mode-coupling approximation predicts loss of ergodicity. These results suggest that the thermodynamically disordered phase of such a minimal model poorly caricatures the slow dynamics of a liquid near its glass transition.
Related Concept Videos
Damped Oscillations
Although friction and other non-conservative...
Theories of Dissolution: The Danckwerts' Model and Interfacial Barrier Model
First Law: Particles in One-dimensional Equilibrium
First Law: Particles in Two-dimensional Equilibrium
Newton's first law tells us about the...
Types of Damping
Limits with Oscillating Discontinuities

