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Updated: Aug 25, 2026

Green Synthesis of Quinoline-Based Ionic Liquid
Published on: September 27, 2024
Superoxide-stable ionic liquids: new and efficient media for electrosynthesis of functional siloxanes
Bruno Martiz1, Robert Keyrouz, Said Gmouh
1Departmento de Química Orgánica, Universidad de Murcia, Spain.
Abstract:
The electrogeneration of diorganylsilanones from difunctional precursors Y(CH(2))(3)(Me)SiX(2) and Ph(2)SiX(2)(Y = NH(2), CF(3), CN; X = Cl, OEt, OMe), performed in the presence of hexamethyldisiloxane or hexamethylcyclotrisiloxane (D(3)) in the ionic liquids [C(5)H(5)NC(8)F(18)].NTf(2), [C(5)H(5)NC(18)H(38)].NTf(2) and Me(3)BuN.NTf(2), which reveal high solubility of oxygen and are inert toward superoxide anion, allows functionalized siloxanes to be produced selectively in good isolated yields.
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