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![The Synthesis of [Sn10(Si(SiMe3)3)4]2- Using a Metastable Sn(I) Halide Solution Synthesized via a Co-condensation Technique](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F54498.jpg&w=3840&q=50)
The Synthesis of [Sn10(Si(SiMe3)3)4]2- Using a Metastable Sn(I) Halide Solution Synthesized via a Co-condensation Technique
Published on: November 28, 2016
Reactions of transition metal clusters with small molecules
1Chemistry Division, Argonne National Laboratory, Argonne, IL 60439, USA. knickelbein@anl.gov
Abstract:
Atoms and small molecules react with transition metal clusters in ways that are analogous to the physisorption and chemisorption reactions observed on the corresponding extended metal surface. However, often underlying these similarities are size-dependent variations in the reaction mechanisms and rates, the interpretation of which requires a detailed understanding of the structures of both the bare metal cluster substrates and the cluster-molecule complexes. Although polyatomic transition metal clusters cannot be characterized by the traditional methods of molecular spectroscopy, the combination of other physical and chemical probes can provide qualitative and semiquantitative structural information. These techniques, when combined with equilibrium geometries calculated using ab initio or semiempirical methods, provide a detailed picture of the structural origin of metal cluster reactivity and its variation with size.
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