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An optical spectroscopic study of borate glasses containing uranium ions
1Technical University of Cluj-Napoca, str. C. Daicoviciu nr. 15, 3400, Cluj-Napoca, Romania.
Analytical and Bioanalytical Chemistry
|June 1, 1996
Abstract:
An optical spectroscopic investigation has been performed on some borate glasses containing 1mol % UF(4), UO(2) and UO(3). The optical data confirm the presence of uranium ions in valence stages of +6, +5 and +4. The influence of the composition of the glass matrix and of the gamma-irradiation on the redox equilibrium of uranium ions was discussed.