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Hydrogen bonded framework structures constructed from 2-(pyridyl N-oxide) methylphosphonic acid ligands and
Xin-Min Gan1, Iris Binyamin, Brian M Rapko
1Department of Chemistry, University of New Mexico, Albuquerque, New Mexico 87131, USA.
Abstract:
Syntheses for 2-(pyridyl N-oxide) methylphosphonic acid, 1-H, and 2-(pyridyl N-oxide) hydroxymethylphosphonic acid, 4-H, are described, and the crystal structures of both ligands are presented. Combination of these ligands with freshly prepared erbium hydroxide results in the formation of the isostructural complexes Er(L(-))(3)(LH).8H(2)O. The crystal structure determinations of the complexes show that extensive hydrogen bonding links the individual eight coordinate Er(L(-))(3)(LH) molecular units into a 3-D structure.
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