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Updated: Aug 25, 2026

Synthesis of Esters Via a Greener Steglich Esterification in Acetonitrile
Published on: October 30, 2018
Paired electrosynthesis of cyanoacetic acid
Belen Batanero1, Fructuoso Barba, Carlos M Sánchez-Sánchez
1Department of Organic Chemistry, University of Alcalá, 28871 Alcalá de Henares, Madrid, Spain.
Abstract:
Cyanoacetic acid is formed by cathodic reduction of CO(2) and anodic oxidation of the tetraalkylammonium salt anion; the process is conduced in acetonitrile using a divided cell with a medium porosity glass-frit diaphragm. A mechanism for this paired electrochemical reaction is proposed.
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