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![The Synthesis of [Sn10(Si(SiMe3)3)4]2- Using a Metastable Sn(I) Halide Solution Synthesized via a Co-condensation Technique](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F54498.jpg&w=3840&q=50)
The Synthesis of [Sn10(Si(SiMe3)3)4]2- Using a Metastable Sn(I) Halide Solution Synthesized via a Co-condensation Technique
Published on: November 28, 2016
Mn14Al56+xGe3-x (x = 0-0.6): a new intermetallic phase containing unprecedented "half-broken" Mackay icosahedra as
1Department of Chemistry and Biochemistry, Arizona State University, Tempe, Arizona, USA.
Abstract:
The new Mn14Al56+xGe3-x (x = 0-0.6) compounds of a new structure type have been synthesized and characterized by physical property measurements and electronic structure calculations. In contrast to their well-known silicon analogues, their unique structure (P) exhibits unprecedented partially destroyed Mackay icosahedra that retain the icosahedral symmetry only in half of the individual polyhedra. The electronic band-structure analysis indicates that the chemical bonding in the structure is still optimized despite the destruction of the Mackay icosahedra and that a further valence electron concentration (VEC) optimization is achieved by the partial occupation of aluminum on a germanium site. The electronic band-structure calculation results were in agreement with the poor metallicity observed for the samples. While the Mn14Al56Ge3 is metallic, the resistivity of Mn14Al56.6Ge2.4 shows a minimum around 20 K and a maximum around 100 K. Both of the samples are Pauli-paramagnetic with an additional small Curie component.
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