Preparation of yttrium oxysulfide phosphor nanoparticles with infrared-to-green and -blue upconversion emission using
Takayuki Hirai1, Takuya Orikoshi
1Research Center for Solar Energy Chemistry and Division of Chemical Engineering, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan. hirai@cheng.es.osaka-u.ac.jp
Abstract:
Yttrium oxysulfide upconverting phosphor nanoparticles, doped with Yb as a sensitizer and Er (or Ho, Tm) as an activator, have been prepared via a solid-gas reaction using precursor oxalate particles obtained in an emulsion liquid membrane (ELM, water-in-oil-in-water (W/O/W) emulsion) system. The resulting Y(2)O(2)S:Yb,Er particles, mainly smaller than 50 nm in diameter, demonstrated green upconversion emission under infrared excitation (lambdaex = 980 nm) via a two-photon process. Distinct green and blue upconversion emission were also demonstrated under the same infrared excitation from Y(2)O(2)S:Yb,Ho and Y(2)O(2)S:Yb,Tm nanoparticles, respectively. These upconverting phosphor nanoparticles, together with Y(2)O(3):Yb,Er infrared-to-red upconverting phosphor particles, with different emission under the same infrared excitation may be applied to the luminescent reporter materials for the detection of the targeted analyte in multiplexed assays.
