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Functional porous coordination polymers.

Susumu Kitagawa1, Ryo Kitaura, Shin-ichiro Noro

  • 1Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nisikyo-ku, Kyoto 615-8510, Japan. Kitagawa@sbchem.kyoto-u.ac.jp

Angewandte Chemie (International Ed. in English)
|April 29, 2004
PubMed
Summary

This review explores porous coordination polymers, focusing on nanospace engineering, functional characterization for storage and separation, and dynamic transformations. It highlights advancements in the chemistry and physics of these materials.

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Area of Science:

  • Materials Science
  • Chemistry
  • Nanotechnology

Background:

  • Coordination polymers have advanced, offering diverse architectures from molecular building blocks.
  • Functionalizing these frameworks, particularly their porous properties, is the next frontier.

Purpose of the Study:

  • To review the state of the art in porous coordination polymers.
  • Focus on nanospace engineering, functional characterization, and dynamic properties.

Main Methods:

  • Crystal engineering for constructing porous frameworks.
  • Characterization and cataloging of porous properties for specific functions.
  • Investigating dynamic crystal transformations.

Main Results:

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  • Porous coordination polymers offer tunable nanospaces via crystal engineering.
  • Functions like storage, separation, and catalysis are achievable.
  • Dynamic transformations enable responsive materials.

    • Conclusions:

    • Porous coordination polymers represent a dynamic field with significant potential.
    • Further research into their chemistry and physics will unlock new applications.