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Factors affecting nitrogen removal by nitritation/denitritation.
P Jenicek1, P Svehla, J Zabranska
1Department of Water Technology and Environmental Engineering, Institute of Chemical Technology Prague, Technicka 5, 166 28 Prague 6, Czech Republic. jenicekp@vscht.cz
Summary
Nitrogen removal from high-concentration wastewater is efficient via nitrite using sequencing batch reactors. Controlling pH and primary sludge addition optimizes nitrogen removal, achieving up to 100% with pH control.
Area of Science:
- Environmental Science
- Water Treatment Engineering
- Microbiology
Background:
- Wastewater treatment often faces challenges with high nitrogen concentrations and low COD/N ratios.
- Nitrogen removal via nitrite offers advantages in specific wastewater streams like sludge liquor.
- Sludge liquor's unique characteristics make it suitable for specialized nitrogen removal processes.
Purpose of the Study:
- To investigate the efficiency of nitrogen removal from high-strength wastewater using nitrite.
- To identify key factors influencing the efficiency of nitrogen removal via nitrite.
- To evaluate the impact of pH control and primary sludge addition on the process.
Main Methods:
- Utilizing sequencing batch reactor (SBR) technology for wastewater treatment.
- Treating wastewater with high ammonium (NH4+) concentrations (above 1 g/l).
- Employing primary sludge as an internal organic substrate source for denitritation.
Main Results:
- Key factors influencing process efficiency include pH, and ammonium/ammonia (NH4+/NH3) and nitrite/nitrous acid (NO2-/HNO2) concentrations.
- Efficient oxidation of ammonium to nitrite was achieved with minimal nitrate production.
- Denitritation was controllable by primary sludge dosing, achieving complete removal under optimal conditions.
Conclusions:
- Nitrogen removal via nitrite in sludge liquor is feasible and advantageous.
- Process efficiency is significantly influenced by pH and substrate availability.
- Two operational strategies exist: lower cost with partial removal (no pH control) or higher cost with complete removal (pH control).