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Polymorphism in biphenyl-based self-assembled monolayers of thiols

Piotr Cyganik1, Manfred Buck

  • 1School of Chemistry, University of St. Andrews, St. Andrews KY16 9ST, UK. pc26@st-and.ac.uk

Journal of the American Chemical Society
|May 13, 2004
PubMed
Summary

Annealing self-assembled monolayers (SAMs) of methylbiphenyl thiols on gold surfaces revealed distinct structural changes and enhanced stability. This suggests new ways to control SAM properties by managing competing energetic factors.

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