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Using stereoelectronic effects to explain selective reactions of 4-substituted five-membered ring oxocarbenium ions
1Department of Chemistry, University of California-Irvine, Irvine, California 92697-2025, USA.
Organic Letters
|June 5, 2004
Abstract:
[reaction: see text] The utility of the inside attack model to predict and analyze the stereoselectivities of nucleophilic additions to complex five-membered ring oxocarbenium ions is demonstrated in a systematic study of C-4-substituted acetals.
![Solid-phase Synthesis of [4.4] Spirocyclic Oximes](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F58508.jpg&w=3840&q=50)
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