Related Experiment Video
Updated: Aug 15, 2026
Chemical Synthesis of Porous Barium Titanate Thin Film and Thermal Stabilization of Ferroelectric Phase by Porosity-Induced Strain
Published on: March 27, 2018
Hydrothermal synthesis and characterization of two organically templated cadmium borophosphates with novel structures
Wei Liu1, Minghui Ge, Xinxin Yang
1The State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Science, Shanghai 200050, China.
Abstract:
Two organically templated cadmium borophosphates, (C(4)H(16)N(3))[CdClB(2)P(3)O(12)(OH)] (1) and (C(2)H(10)N(2))[CdB(2)P(3)O(12)(OH)] (2), were synthesized hydrothermally in the presence of structure-directing amines. Compound 1 has a complex layered structure (orthorhombic, Pbca (No. 61); a = 9.470(2), b = 12.307(3), c = 27.311(6) A; V = 3183 (1) A(3); Z = 8) with a 9MR channel system, while compound 2 (orthorhombic, Pbca (No. 61); a = 9.286(3), b = 12.459(3), c = 21.626(6) A; V = 2502(1) A(3); Z = 8) presents a 3-dimensional open framework structure of different types of intersecting channels. It is worth noting that both the Cl(-) anions and the organic templates play important and interesting roles in the formation of the structures.
More Related Videos
07:14Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
Published on: May 12, 2023
07:20Discovery and Synthesis Optimization of Isoreticular Al(III) Phosphonate-Based Metal-Organic Framework Compounds Using High-Throughput Methods
Published on: October 6, 2023