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Updated: Jul 22, 2026

Measurement of Ultrafast Vibrational Coherences in Polyatomic Radical Cations with Strong-Field Adiabatic Ionization
Published on: August 6, 2018
Measurement of large distances in biomolecules using double-quantum filtered refocused electron spin-echoes
Peter P Borbat1, Jared H Davis, Samuel E Butcher
1Department of Chemistry and Chemical Biology, B52 Baker Lab, Cornell University, Ithaca, New York 14853, USA.
Abstract:
It is shown how the new technique of double-quantum filtered refocused electron spin-echoes is a significant improvement over double-quantum coherence ESR, since it increases the experimental acquisition time. This enables the measurement of longer distances in bilabeled biomolecules. The method is demonstrated on a long double-stranded A-type RNA, spin labeled at both ends. The measured distance of 72 A is in excellent agreement with molecular modeling.
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