Related Experiment Video
Updated: Aug 23, 2026

07:56
Preparation of 6-aminocyclohepta-2,4-dien-1-one Derivatives via Tricarbonyl(tropone)iron
Published on: August 12, 2019
Dichloro(methanol-kappaO)[(methoxy)tris(1-methyl-1H-imidazol-2-yl)methane-kappa2N3]iron(II) (ca 153 K)
Michael P Batten1, Allan J Canty, Kingsley J Cavell
1Department of Chemistry, University of Tasmania, Hobart, 7001, Australia.
Abstract:
In the quasi-trigonal-bipyramidal environment of the five-coordinate Fe(II) atom in the title compound, [FeCl2(C14H18N6O)(CH4O)], the methanol and one of the N-atom donors of the potentially tridentate ligand are disposed axially: Fe-N(axial) is 2.149 (2) A, Fe-N(equatorial) is 2.108 (2) A and N-Fe-O is 174.14 (7) degrees.

