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Poly(guanidyl)silanes as a new class of chelating, N-based ligand

Sarah H Oakley1, Martyn P Coles, Peter B Hitchcock

  • 1The Chemistry Department, University of Sussex, Falmer, Brighton, BN1 9QJ, UK.

Dalton Transactions (Cambridge, England : 2003)
|July 15, 2004
PubMed

Abstract:

The series of poly(guanidyl)silanes RnSi[hpp](4-n) [hpp = 1,3,4,6,7,8-hexahydro-2Hpyrimido[1,2-a]pyrimidinate; R = Me, n= 1, 2; R = Ph, n= 1] have been synthesised and their coordination behaviour at copper(I) halides investigated.

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