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Potassium barium bismuth oxide.

G Derrien1, M Tillard, L Monconduit

  • 1Laboratoire des Agrégats Moléculaires et Matériaux Inorganiques, UMR 5072 CC15, Université des Sciences et Techniques du Languedoc, 2 Place Eugène Bataillon, 34095 Montpellier CEDEX 5, France.

Acta Crystallographica. Section C, Crystal Structure Communications
|July 21, 2004
PubMed
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This study reveals the crystal structure of KBa(4)Bi(3)O, detailing the unique arrangements of bismuth ions. Bismuth exists as both Bi(3-) anions and Bi(2)(4-) dumbbells within the tetragonal structure.

Area of Science:

  • Solid-state chemistry
  • Crystallography
  • Materials science

Background:

  • Understanding complex oxide structures is crucial for developing new materials.
  • Bismuth-containing compounds exhibit diverse structural and electronic properties.

Purpose of the Study:

  • To elucidate the crystal structure of the novel compound KBa(4)Bi(3)O.
  • To characterize the coordination environments of bismuth and oxygen atoms.

Main Methods:

  • Single-crystal X-ray diffraction.
  • Space group determination (I4/mcm).
  • Analysis of atomic coordination and bonding.

Main Results:

  • KBa(4)Bi(3)O crystallizes in the centrosymmetric tetragonal space group I4/mcm.

Related Experiment Videos

  • Bismuth exists as isolated Bi(3-) anions and Bi(2)(4-) dumbbells (Bi-Bi bond length 3.113 Å).
  • Specific coordination polyhedra for Bi1 (bicapped square antiprism) and Bi2 (bicapped distorted trigonal prism) were identified.
  • Conclusions:

    • The crystal structure of KBa(4)Bi(3)O is characterized by distinct bismuth anionic species.
    • Oxygen atoms are located in tetrahedral voids between barium atoms.
    • This structural insight provides a foundation for exploring the properties of this bismuth-containing oxide.