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Updated: Aug 5, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
(o-Benzoquinone diimine-N,N')dichlorobis(triphenylphosphine-P)ruthenium(II) 1.33-methanol 0.33-dichloromethane
Diego Venegas-Yazigi1, Hameed Mirza, A. B. P. Lever
1Departamento de Química, Facultad de Ciencias, Universidad de Chile, Casilla 653, Santiago, Chile.
Abstract:
The Ru atom in the title compound, [RuCl(2){P(C(6)H(5))(3)}(2){C(6)H(4)(NH)(2)}].1.33CH(3)OH.0.33CH(2)Cl(2), shows a six-coordinate octahedral geometry, with a trans arrangement of the triphenylphosphine groups. One and a half molecules of complex, two molecules of methanol and a half molecule of dichloromethane form the asymmetric unit, with crystallographic twofold rotation symmetry for the complex molecule in a special position.
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