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Updated: Aug 23, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
micro-Chloro-bis{[benzylbis(2-pyridylmethyl)amine-kappa(3)N]chlorocopper(II)} perchlorate hemihydrate
Yoshiyuki Kani1, Shigeru Ohba, Sayo Ito
1Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, Yokohama 223-8522, Japan.
Abstract:
In the title dinuclear Cu(II) compound, [Cu(2)Cl(3)(C(19)H(19)N(3))(3)]ClO(4).0.5H(2)O, the coordination geometry around the Cu atoms is square pyramidal, with the bridging Cl atom at the apical positions. The Cu-Cl-Cu angle is 136.9 (1) degrees and the Cu.Cu distance is 4.961 (1) A.
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