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Bis(N,N-diethyl-1,1-diselenocarbamato-Se)selenium, [(Se(2)CNEt(2))(2)Se]
1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Fuzhou, Fujian 350002, People's Republic of China.
Abstract:
The polyseleno title compound, bis(N,N-diethylselenocarbamoyl) triselenide, [(Se(2)CNEt(2))(2)Se] or C(10)H(20)N(2)Se(5), is obtained from the disproportion of sodium N,N-diethyl-1,1-diselenocarbamate. An Se atom connects two N,N-diethyl-1,1-diselenocarbamate groups with Se-Se distances in the range 2.4500 (11)-2.8601 (12) A