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Updated: Aug 23, 2026

One-pot Microwave-assisted Conversion of Anomeric Nitrate-esters to Trichloroacetimidates
Published on: January 15, 2018
trans-1-Cyano-2-(2-methoxyphenyl)-1-nitroethylene
V N Nesterov1, V P Kislyi, T V Timofeeva
1Department of Physical Sciences, New Mexico Highlands University, Las Vegas, NM 87701, USA, and Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov St, B-334 Moscow, Russian Federation.
Abstract:
The title compound, C(10)H(8)N(2)O(3), has been prepared by condensation of 2-methoxybenzaldehyde and nitroacetonitrile in ethanol at room temperature. Its investigation has been undertaken as a part of search for new nonlinear optical compounds. The pi-conjugated molecule is almost planar. Molecules in the crystal are packed in stacks with antiparallel molecular orientation and slightly alternating distances between mean molecular planes.
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