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Updated: Aug 23, 2026

Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst
Published on: April 22, 2016
Recent progress toward the exploitation of organic radical compounds with photo-responsive magnetic properties
1Department of Material Science, Graduate School of Science, Himeji Institute of Technology, Koto 3-2-1, Kamigori, Hyogo 678-12, Japan.
Abstract:
Recent studies on the exploitation of novel organic radical compounds that exhibit photo-responsive properties by illumination are described in this tutorial review. Those so far reported consist of a variety of photo-responsive pi-electron moieties such as azobenzene, diarylethene, biindenylidene, terphenoquinone, anthracene, naphthopyran, arylimine, or hexaarylbiimidazoles, bearing stable organic radicals or generating organic radicals as spin centres for magnetic properties. The switching behaviours of their magnetic properties evoked by the stimuli of irradiation are discussed by taking the associated structural changes into consideration.
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