Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

Silicate complexes of sugars in aqueous solution.

Joseph B Lambert1, Gang Lu, Stephanie R Singer

  • 1Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA. jlambert@northwestern.edu

Journal of the American Chemical Society
|August 5, 2004
PubMed
Summary
This summary is machine-generated.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Identification of a Novel Ichthyic Parvovirus in Marine Species in Hainan Island, China.

Frontiers in microbiology·2019
Same author

MnO<sub>2</sub> Nanosheet-Assembled Hollow Polyhedron Grown on Carbon Cloth for Flexible Aqueous Zinc-Ion Batteries.

ChemSusChem·2019
Same author

Self-Healing of Photocurrent Degradation in Perovskite Solar Cells: The Role of Defect-Trapped Excitons.

The journal of physical chemistry letters·2019
Same author

Corrigendum: Emergence of Getah Virus Infection in Horse With Fever in China, 2018.

Frontiers in microbiology·2019
Same author

Getah virus: An increasing threat in China.

The Journal of infection·2019
Same author

African swine fever virus in Asia: Its rapid spread and potential threat to unaffected countries.

The Journal of infection·2019

Certain sugars form soluble silicate complexes with silicic acid, but only specific furanose forms react. This selective reaction, involving the anomeric hydroxyl group, has implications for prebiotic chemistry.

Area of Science:

  • Carbohydrate Chemistry
  • Silicate Chemistry
  • Prebiotic Chemistry

Background:

  • Sugars can react with silicic acid to form soluble silicate complexes.
  • The structure of the sugar and its configuration are critical for complex formation.

Purpose of the Study:

  • To investigate the structural requirements for sugar-silicic acid complex formation.
  • To understand the selectivity of this reaction and its potential implications.

Main Methods:

  • Nuclear Magnetic Resonance (NMR) spectroscopy, specifically (29)Si and (13)C NMR, was used to analyze the products.
  • Studied the reaction of various monosaccharides and disaccharides with basic silicic acid.

Main Results:

  • Only furanose forms of sugars reacted with silicic acid, forming 2/1 (sugar/silicic acid) chelates.

Related Experiment Videos

  • Reaction requires the anomeric hydroxyl group to be cis to an adjacent hydroxyl group.
  • Specific sugars like ribose, xylose, and fructose formed complexes, while glucose and galactose did not.

    • Conclusions:

    • Sugar silicate complex formation is highly selective, depending on sugar structure and hydroxyl group configuration.
    • The reaction mechanism involves chelation via a five-membered diolato ring.
    • This selectivity may play a role in prebiotic chemical processes.